Safety Data Sheet - Hand Sanitizer

University of Nebraska–Lincoln

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name

:

HAND SANITIZER

Other means of identification

:

not applicable

Recommended use

:

Hand Sanitizer

Restrictions on use

:

Reserved for industrial and professional use.

Product dilution information

:

Product is ready to use.

Company

:

University of Nebraska - Lincoln Nebraska Innovation Campus Lincoln, NE

1-402-472-2142

Emergency telephone

:

1-800-424-9300 (US)

Issuing date

:

04/7/2020

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification

Flammable liquids

:

Category 3

Eye irritation

:

Category 2A

GHS Label element

Hazard pictograms

:

hazard pictogram

hazard pictogram

Signal Word

:

Warning

Hazard Statements

:

Flammable liquid and vapor.

Causes serious eye irritation.

Precautionary Statements

:

Prevention:

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed.

Response:

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.

Storage:

Store in a well-ventilated place. Keep cool.

Disposal:

Dispose of contents/ container to an approved waste disposal plant.

Other hazards

:

None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Pure substance/mixture

:

Mixture

Chemical Name

CAS-No. Concentration (%)

ethanol

hydrogen peroxide

glycerin water

64-17-5

7722-84-1

56-81-5

7732-18-5

80%

< 1%

< 2%

17-18%

SECTION 4. FIRST AID MEASURES

In case of eye or skin contact If swallowed

If inhaled

Protection of first-aiders Notes to physician

: Rinse with water.

: Rinse mouth. Get medical attention if symptoms occur.

: Get medical attention if symptoms occur.

: No special precautions are necessary for first aid responders. : Treat symptomatically.

See toxicological information (Section 11)

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media

:

Use extinguishing measures that are appropriate to local

circumstances and the surrounding environment.

Unsuitable extinguishing

media

:

High volume water jet

Specific hazards during fire fighting

:

Fire Hazard

Keep away from heat and sources of ignition. Flash back possible over considerable distance.

Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas.

Hazardous combustion

products

:

Carbon oxides

Special protective equipment

for fire-fighters

:

Use personal protective equipment.

Specific extinguishing methods

:

Use water spray to cool unopened containers. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion

do not breathe fumes.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions,

protective equipment and emergency procedures

:

Remove all sources of ignition. Ensure clean-up is conducted by

trained personnel only. Refer to protective measures listed in sections 7 and 8.

Environmental precautions

:

Do not allow contact with soil, surface or ground water.

Methods and materials for containment and cleaning up

:

Eliminate all ignition sources if safe to do so. Stop leak if safe to do so. Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach

a waterway.

SECTION 7. HANDLING AND STORAGE

Advice on safe handling

:

Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors). Keep away from fire, sparks

and heated surfaces.

Conditions for safe storage

:

Keep away from heat and sources of ignition. Keep in a cool, well- ventilated place. Keep away from oxidizing agents. Keep out of reach of children. Keep container tightly closed. Store in suitable labeled

containers.

Storage temperature

:

0 °C to 35 °C

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Ingredients

CAS-No.

Form of exposure

Permissible concentration

Basis

ethanol

64-17-5

TWA

1,000 ppm

ACGIH

TWA

1,000 ppm

1,900 mg/m3

NIOSH REL

TWA

1,000 ppm

1,900 mg/m3

OSHA Z1

Engineering measures

:

Good general ventilation should be sufficient to control worker

exposure to airborne contaminants.

Personal protective equipment

Eye protection

:

No special protective equipment required.

Hand protection

:

No special protective equipment required.

Skin protection

:

No special protective equipment required.

Respiratory protection

:

No personal respiratory protective equipment normally required.

Hygiene measures

:

No specific measures identified.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Initial boiling point and boiling range

: liquid

Appearance

Color

Odor

pH

Flash point

Odor Threshold

Melting point/freezing point

: opaque, white

: alcoholic

: 6.3 - 8.5, 100 %

: 23 °C closed cup

: no data available

: no data available

: no data available

Evaporation rate

:

no data available

Flammability (solid, gas)

:

no data available

Upper explosion limit

:

no data available

Lower explosion limit

:

no data available

Vapor pressure

:

no data available

Relative vapor density

:

no data available

Relative density

:

0.869 - 0.873

Water solubility

:

no data available

Solubility in other solvents

:

no data available

Partition coefficient: n- octanol/water

:

no data available

Autoignition temperature

:

no data available

Thermal decomposition

:

no data available

Viscosity, kinematic

:

no data available

Explosive properties

:

no data available

Oxidizing properties

:

no data available

Molecular weight

:

no data available

VOC

:

no data available

SECTION 10. STABILITY AND REACTIVITY

Chemical stability

:

Stable under normal conditions.

Possibility of hazardous

reactions

:

No dangerous reaction known under conditions of normal use.

Conditions to avoid

:

Heat, flames and sparks.

Incompatible materials

:

None known.

Hazardous decomposition

products

:

Carbon oxides

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of

exposure

:

Inhalation, Eye contact, Skin contact

Potential Health Effects

Eyes

:

Causes serious eye irritation.

Skin

:

Health injuries are not known or expected under normal use.

Ingestion

:

Health injuries are not known or expected under normal use.

Inhalation

:

Health injuries are not known or expected under normal use.

Chronic Exposure

:

Health injuries are not known or expected under normal use.

Experience with human exposure

Eye contact

:

Redness, Pain, Irritation

Skin contact

:

No symptoms known or expected.

Ingestion

:

No symptoms known or expected.

Inhalation

:

No symptoms known or expected.

Toxicity

Acute oral toxicity

:

Acute toxicity estimate > 5,000 mg/kg

Acute inhalation toxicity

:

no data available

Acute dermal toxicity

:

no data available

Skin corrosion/irritation

:

no data available

Serious eye damage/eye irritation

:

no data available

Respiratory or skin sensitization

:

no data available

Carcinogenicity

IARC

No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human

carcinogen by IARC.

OSHA

No ingredient of this product present at levels greater than or equal to

0.1% is identified as a carcinogen or potential carcinogen by OSHA.

NTP

No ingredient of this product present at levels greater than or equal to

0.1% is identified as a known or anticipated carcinogen by NTP.

Reproductive effects

:

no data available

Germ cell mutagenicity

:

no data available

Teratogenicity

:

no data available

STOT-single exposure

:

The substance or mixture is not classified as specific target organ toxicant, single exposure.

STOT-repeated exposure

:

no data available

Aspiration toxicity

:

no data available

Ingredients

Acute inhalation toxicity

:

ethanol

4 h LC50 rat: 117 mg/l

Ingredients

Acute dermal toxicity

:

ethanol

LD50 rabbit15,800 mg/kg

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Environmental Effects

:

Harmful to aquatic life.

Product

Toxicity to fish

:

no data available

Toxicity to daphnia and other aquatic invertebrates

:

no data available

Toxicity to algae

:

no data available

Ingredients

Toxicity to fish

:

ethanol

96 h LC50 Fish: 11,000 mg/l

Persistence and degradability

no data available

Bioaccumulative potential

no data available

Mobility in soil

no data available

Other adverse effects

no data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods

:

The product should not be allowed to enter drains, water courses or the soil. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste

disposal facility.

Disposal considerations

:

Dispose of as unused product. Empty containers should be taken to

an approved waste handling site for recycling or disposal. Do not re- use empty containers.

RCRA - Resource Conservation and Recovery

Authorization Act Hazardous waste

:

D001 (Ignitable)

SECTION 14. TRANSPORT INFORMATION

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport.

Land transport (DOT)

UN number

:

1170

Description of the goods

:

Ethanol solutions

Class

:

3

Packing group

:

III

Environmentally hazardous

:

no

: 1987

: Alcohols, n.o.s,

: 3

OR : II

: no

Sea transport (IMDG/IMO)

UN number

:

1170

Description of the goods

:

ETHANOL SOLUTION

Class

:

3

Packing group

:

III

Marine pollutant

:

no

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know

CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RQ.

SARA 304 Extremely Hazardous Substances Reportable Quantity

This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards

:

Fire Hazard

Acute Health Hazard

SARA 302

:

SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313

:

SARA 313: This material does not contain any chemical components

with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

California Prop 65

This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects.

The ingredients of this product are reported in the following inventories: 1907/2006 (EU) :

not determined

United States TSCA Inventory :

On TSCA Inventory

Canadian Domestic Substances List (DSL) :

This product contains one or several components that are not on the Canadian DSL nor NDSL.

SECTION 16. OTHER INFORMATION

NFPA:

HMIS III:

NFPA image3

2

0

Flammability

Instability

Health

HEALTH

2

FLAMMABILITY

3

PHYSICAL HAZARD

0

Special hazard.

0 = not significant, 1 =Slight,

2 = Moderate, 3 = High 4 = Extreme, * = Chronic

Issuing date

Version

Prepared by

: 04/07/2020

: 1.0

: EHS

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.